Thamaraikannan, Thangavel and Karthikeyan, P. and Sasieekhumar, A. R. and Rathinavelu, Arumugam and Poovarasan, Madheswaran and Saravanakumar, Rathinavel and Srinivasan, P. and Rajavel, Rangappan (2025) Electrochemical analysis of g-C3N4-ferulic acid composite on the glassy carbon electrode surface and its electrocatalytic activity of dopamine oxidation and sensing. Applied Physics A: Materials Science and Processing, 131 (8). ISSN 09478396; 14320630
Full text not available from this repository.Abstract
Graphene-based materials show promise for electrochemical sensors, but developing a straightforward synthesis method and understanding how their structure influences performance remains a challenge. Eco-friendly, the synthesis of graphene material like graphite nitrite (g-C3N4) immobilized with organic compounds like ferulic acid (FA) is recent research due to its stability, sensitivity, and selectivity. We proposed g-C3N4-FA (carbon nitride embedded ferulic acid) for electrochemical analysis. Ferulic acid is a phytochemical with polyphenolic functional groups utilized extensively as an anti-oxidant, anti-cancer, and anti-aging cosmetic agent. Only in organic media has FA recognized as a stable redox-active system; in aqueous solutions, it is irreversibly oxidized with linked chemical processes exhibiting vague redox peaks. It�s interesting to note that when FA-tethered g-C3N4 was electrooxidized, a distinct pair of redox peaks with surface-confined properties were visible at = 0.20 V versus Ag/AgCl, which corresponded to the ortho-quinone moiety of oxidized FA in pH 7 phosphate buffer solution (PBS). Cyclic voltammetry (CV) was used to analyze the GCE@g-C3N4-FA. FTIR, SEM, and Raman spectroscopy were used to characterize the physicochemical properties of g-C3N4-FA. The GCE@g-C3N4-FA showed excellent electrocatalytic activity toward dopamine oxidation. The mechanism and kinetics of the catalytic reaction were investigated by CV and amperometric i-t for highly selective sensing of dopamine without any interference from other biochemicals were validated. © 2025 Elsevier B.V., All rights reserved.
| Item Type: | Article |
|---|---|
| Additional Information: | Cited by: 1 |
| Uncontrolled Keywords: | Carbon phenolic composites; Catalytic oxidation; Chemical detection; Chlorine compounds; Electrochemical electrodes; Electrochemical sensors; Functional groups; Graphene; Graphitic Carbon Nitride; Neurophysiology; Physicochemical properties; Quinone; Redox reactions; Dopamine; Dopamine oxidation; Dopamine sensing; Electrocatalytic activity; Electrochemical analysis; Electrochemical sensing; Ferulic acids; G-c3n4-ferulic acid; Graphitic carbon nitrides; Cyclic voltammetry |
| Subjects: | Chemistry > Analytical Chemistry |
| Divisions: | Medicine > Vinayaka Mission's Kirupananda Variyar Medical College and Hospital, Salem |
| Depositing User: | Unnamed user with email techsupport@mosys.org |
| Last Modified: | 14 Oct 2025 18:03 |
| URI: | https://vmuir.mosys.org/id/eprint/89 |
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