Electrochemical analysis of g-C3N4-ferulic acid composite on the glassy carbon electrode surface and its electrocatalytic activity of dopamine oxidation and sensing

Thamaraikannan, Thangavel and Karthikeyan, P. and Sasieekhumar, A. R. and Rathinavelu, Arumugam and Poovarasan, Madheswaran and Saravanakumar, Rathinavel and Srinivasan, P. and Rajavel, Rangappan (2025) Electrochemical analysis of g-C3N4-ferulic acid composite on the glassy carbon electrode surface and its electrocatalytic activity of dopamine oxidation and sensing. Applied Physics A: Materials Science and Processing, 131 (8). ISSN 09478396; 14320630

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Abstract

Graphene-based materials show promise for electrochemical sensors, but developing a straightforward synthesis method and understanding how their structure influences performance remains a challenge. Eco-friendly, the synthesis of graphene material like graphite nitrite (g-C3N4) immobilized with organic compounds like ferulic acid (FA) is recent research due to its stability, sensitivity, and selectivity. We proposed g-C3N4-FA (carbon nitride embedded ferulic acid) for electrochemical analysis. Ferulic acid is a phytochemical with polyphenolic functional groups utilized extensively as an anti-oxidant, anti-cancer, and anti-aging cosmetic agent. Only in organic media has FA recognized as a stable redox-active system; in aqueous solutions, it is irreversibly oxidized with linked chemical processes exhibiting vague redox peaks. It�s interesting to note that when FA-tethered g-C3N4 was electrooxidized, a distinct pair of redox peaks with surface-confined properties were visible at = 0.20 V versus Ag/AgCl, which corresponded to the ortho-quinone moiety of oxidized FA in pH 7 phosphate buffer solution (PBS). Cyclic voltammetry (CV) was used to analyze the GCE@g-C3N4-FA. FTIR, SEM, and Raman spectroscopy were used to characterize the physicochemical properties of g-C3N4-FA. The GCE@g-C3N4-FA showed excellent electrocatalytic activity toward dopamine oxidation. The mechanism and kinetics of the catalytic reaction were investigated by CV and amperometric i-t for highly selective sensing of dopamine without any interference from other biochemicals were validated. © 2025 Elsevier B.V., All rights reserved.

Item Type: Article
Additional Information: Cited by: 1
Uncontrolled Keywords: Carbon phenolic composites; Catalytic oxidation; Chemical detection; Chlorine compounds; Electrochemical electrodes; Electrochemical sensors; Functional groups; Graphene; Graphitic Carbon Nitride; Neurophysiology; Physicochemical properties; Quinone; Redox reactions; Dopamine; Dopamine oxidation; Dopamine sensing; Electrocatalytic activity; Electrochemical analysis; Electrochemical sensing; Ferulic acids; G-c3n4-ferulic acid; Graphitic carbon nitrides; Cyclic voltammetry
Subjects: Chemistry > Analytical Chemistry
Divisions: Medicine > Vinayaka Mission's Kirupananda Variyar Medical College and Hospital, Salem
Depositing User: Unnamed user with email techsupport@mosys.org
Last Modified: 14 Oct 2025 18:03
URI: https://vmuir.mosys.org/id/eprint/89

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