Hydrogen sulfide, methane, VOCs, and other odorous compounds from municipal solid waste (MSW) dumping sites impact human health and the environment. This study analyzed VOC emissions using GC-MS and surveyed health risks to workers. Maximum VOC concentration was tert-butylbenzene (1.41 µg/m3) and minimum Sec-butylbenzene (0.07 µg/m3). Findings indicate VOC exposure causes non-cancerous health effects affecting vital organs and contributes to environmental issues like global warming. Effective management of VOC emissions during composting is necessary to reduce health risks and environmental impact.