A novel Cadmium metal-organic framework with exceptional nonlinear optical properties: Unveiling anisotropic charge transport and optical limiting behavior

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Catherine Paul, Anaglit and Hemamalini, Madhukar and Mustaqim Rosli, Mohd and Jose Kavitha, Savaridassan and Rajakannan, Venkatachalam and Anbazhagan, V. and Stephen Arputharaj, David and Al-sehemi, Abdullah G. and Balasubramani, Kasthuri and Alwani Zainuri, Dian and Abdul Razak, Ibrahim (2024) A novel Cadmium metal-organic framework with exceptional nonlinear optical properties: Unveiling anisotropic charge transport and optical limiting behavior. Results in Chemistry, 7. p. 101277. ISSN 22117156

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Abstract

A novel non-centrosymmetric Cadmium Metal-Organic Framework (Cd-MOF) crystal with chemical formula CdC8N8H14O2S4 was synthesized and characterized. The band structure and optical limiting properties of the Cd-MOF were investigated using Band structure calculations and Optical limiting studies. The band structure analysis showed that the crystal displayed a larger, highly dispersive band, highlighting significant anisotropic n-channel charge carrier mobility. The optical limiting study demonstrated that the Cd-MOF exhibited Reverse Saturable Absorption (RSA) behaviour with an optical limiting threshold value of 1094 kW/cm2. The NLO behaviour of the Cd-MOF provides a promising potential for its application in NLO devices. © 2024 Elsevier B.V., All rights reserved.

Item Type: Article
Subjects: Chemistry > Inorganic Chemistry
Divisions: Medicine > Vinayaka Mission's Kirupananda Variyar Medical College and Hospital, Salem > Biochemistry
Depositing User: Unnamed user with email techsupport@mosys.org
Last Modified: 27 Nov 2025 07:04
URI: https://vmuir.mosys.org/id/eprint/2036

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